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Horsepower hour (2,684,519 J)
A horsepower-hour (hph or hp⋅h) is an outdated unit of energy, not used in the SI system of units. The unit represents an amount of work a horse is supposed capable of delivering during an hour (1 (one) horsepower integrated over a time interval of an hour). The horsepower-hour is still used in the railroad industry when sharing motive power (locomotives.) For example, if Railroad A borrows a 2,500 horsepower locomotive from Railroad B and operates it for twelve hours, Railroad A owes a debt of (2,500 hp × 12 h) = 30,000 hp⋅h. Railroad A may repay the debt by loaning Railroad B a 3,000 horsepower locomotive for ten hours.
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Calorie (Thermochemical) (4.19 J)
A calorie is a unit of energy. Various definitions exist but fall into two broad categories. The first, the small calorie, or gram calorie (symbol: cal), is defined as the amount of energy needed to raise the temperature of one gram of water by one degree Celsius at a pressure of one atmosphere. The second, the large calorie or kilogram calorie (symbols: Cal, kcal), also known as the food calorie and similar names, is defined in terms of the kilogram rather than the gram. It is equal to 1000 small calories or 1 kilocalorie (symbol: kcal). In other scientific contexts, the term calorie almost always refers to the small calorie. Even though it is not an SI unit, it is still used in chemistry. For example, the energy released in a chemical reaction per mole of reagent is occasionally expressed in kilocalories per mole. Typically, this use was largely due to the ease with which it could be calculated in laboratory reactions, especially in aqueous solution: a volume of reagent dissolved in water forming a solution, with concentration expressed in moles per liter (1 liter weighing 1 kg), will induce a temperature change in degrees Celsius in the total volume of water solvent, and these quantities (volume, molar concentration and temperature change) can then be used to calculate energy per mole. It is also occasionally used to specify energy quantities that relate to reaction energy, such as enthalpy of formation and the size of activation barriers. However, its use is being superseded by the SI unit, the joule, and multiples thereof such as the kilojoule.